Liverpool won the competition - then called the Carling Cup - in the season just concluded, beating Cardiff 3-2 on penalties at Wembley in February.
The value of the new sponsorship deal with the credit card company was not disclosed.
Football League chief commercial officer Richard Heaselgrave said: "This is terrific news for clubs and a great way to conclude what has been a memorable domestic football season...
"The Capital One Cup is in great shape having been re-invigorated in recent seasons by a number of memorable finals, some thrilling midweek cup football and a first glimpse of the stars of the future."
The draw for the first round of the rebranded competition will be made on June 14th, with the final scheduled to take place at Wembley on February 24.
The Liverpool 2013/14 soccer jersey is available for pre-order. The Reds are eager to compete for silver next season.
Borussia Dortmund hears Wembley Calling and are headed to London for the Champions League final.
The Juventus jersey for the 2013/14 was released earlier this week. Be the first to wear the colors of the Old Lady.
adidas has added some color to the Predator line with this new colorway. Released on May 17. Be the first to own a pair.
Ajax has released their away soccer jersey for the 2013/14 season. Get in the Gear.
The adidas Nitrocharge is the most talked about new cleat in years. It was released on May 15 and will take your pitch by storm.
One of the top soccer cleats for control the Nike CTR360 will not let you down on the field in tight spaces.
The new PUMA evoSPEED 1.2 FG. A great new soccer cleat with classic look and first time for PUMA to be on the cleat.
Bayern Munich are kings of Germany and hope to be crowned kings of Europe at Wembley later this month!
The push for more color on their cleats, adidas has added the infrared colorway to the adiZero f50 Line.