Chievo ended a five-game losing streak with the 2-1 success at the Stadio Bentegodi.
Corini replaced Domenico di Carlo earlier this week, although it seemed like he may have to settle for a point in his first match when Samp midfielder Enzo Maresca scored direct from a free-kick after Cyril Thereau had given the Flying Donkeys a half-time lead.
But David Di Michele tried his luck from distance and Sampdoria keeper Sergio Romero made a hash of his attempt to keep it out, gifting Chievo victory three minutes from time.
Also on Saturday, Gian Piero Gasperini made an emotional return to the Stadio Luigi Ferraris in Palermo's 1-1 draw at former club Genoa.
Gasperini had led Il Grifone into the Europa League in 2009, spending over four years at the club, and he looked to be on course for three points tonight when Luigi Giorgi put Palermo ahead in the 14th minute.
Marco Borriello rescued a share of the spoils for Genoa seven minutes after the interval.
Borussia Dortmund hears Wembley Calling and are headed to London for the Champions League final.
The push for more color on their cleats, adidas has added the infrared colorway to the adiZero f50 Line.
Ajax has released their away soccer jersey for the 2013/14 season. Get in the Gear.
Chelsea won the Europa League on Wednesday. The Blues defeated Benfica 2-1 on injury time goal from Ivanovic.
One of the top soccer cleats for control the Nike CTR360 will not let you down on the field in tight spaces.
The Liverpool 2013/14 soccer jersey is available for pre-order. The Reds are eager to compete for silver next season.
adidas has added some color to the Predator line with this new colorway. Released on May 17. Be the first to own a pair.
Bayern Munich are kings of Germany and hope to be crowned kings of Europe at Wembley later this month!
The adidas Nitrocharge is the most talked about new cleat in years. It was released on May 15 and will take your pitch by storm.
The new PUMA evoSPEED 1.2 FG. A great new soccer cleat with classic look and first time for PUMA to be on the cleat.