The Premier League fixtures were released on Monday on the same day that Clarke was unveiled as the new Albion boss.
They threw up an intriguing opening day clash between the Clarke's new team and the club where he worked as Kenny Dalglish's assistant before his fellow Scot was sacked recently.
Clarke, who is undertaking his first job as a head coach following 14 years as a number two, said: "I was delighted to get Liverpool first game.
"I've got nothing but good memories from my time at Liverpool so to face them in the first game, here at the Hawthorns, will be fantastic.
"It takes a lot to get me really excited (when I heard), I was excited."
Clarke has established himself as one of the game's leading coaches having worked under the likes of the late Sir Bobby Robson, Jose Mourinho and Dalglish.
He admits his first job as a boss is somewhat overdue.
"Obviously when I left Chelsea in 2008 it was with the ambition to become a manager or head coach in my own right," he said.
"I could have stayed at Chelsea for as long as I wanted and been as comfortable as I wanted but I decided to get out of my comfort zone.
"To be honest I thought this position, or this appointment, would have come about a little bit sooner. Circumstances dictated that it didn't.
"Obviously losing my job at Liverpool in the summer was disappointing but then very quickly this opportunity came up to talk to West Brom.
"I was really impressed with what they had to say and it just feels like the right appointment at the right time for me."
Clarke has vowed to try to play attacking football at The Hawthorns built on solid defensive foundations.
"I don't want to lose the strengths that the club had last season," he said. "They were really well-organised, disciplined and hard to beat. That is the first priority for anybody. On top of that I'd like to add my own little stamp and we can hopefully become a little bit more attacking, especially at home."
Clarke revealed he spoke to old Chelsea team-mate and former West Brom boss Roberto Di Matteo about Albion before taking the job, while Mourinho has also been in touch.
"When I knew I had a chance of getting the job here, I spoke to Roberto about the club," Clarke said. "He had really good things to say about Albion and the people at the club, so it's been helpful to speak to him.
"I've had a text message from Jose - he's on holiday just now, so I don't want to disturb his holidays."
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