Leading 1-0 from the first leg in Madrid on Wednesday, Valladolid were pegged back just before half-time when Fernando Sales headed the visitors level on aggregate.
However, Javi Guerra, who had scored the winner at Santo Domingo earlier in the week, was on target again six minutes after the break to ensure a return to the top flight after a two-year absence.
Miroslav Dukic's men had missed out on automatic promotion by just three points as they finished third behind Celta Vigo and champions Deportivo La Coruna, a full nine points ahead of Alcorcon in fourth.
Germany is one of the top teams ever and they will play the US on Sunday.
The Nike Hypervenom is the latest cleat silo from Nike. It will change your game and is worn by the game's top players.
Jamaica is in need of a win against the U.S. Get the jersey of the Reggae Boyz.
The adidas Nitrocharge is the most talked about new cleat in years. It was released on May 15 and will take your pitch by storm.
Barcelona will wear this new home soccer jersey next season. They also have a new away jersey. Get them both.
The USA will wear their blue away jersey against Jamaica in their World Cup qualifier on Friday night.
The hoop soccer jersey is classic and cool. The USA hooped jersey is perfect for every fan. Get in the Gear.
England will debut their new away jersey against Brazil at the Maracana Stadium on Sunday. Get in the Gear
Manchester City will try and win back the Premier League title with this new soccer jersey from Nike!
Neymar's move from Santos to Barcelona is no doubt the biggest summer transfer.