The game will mark Stale Solbakken's first cup tie in charge of Wolves after taking over from Terry Connor in May as Wolves were relegated from the Premier League.
Last season's runners-up Cardiff City begin their campaign away at Aidy Boothroyd's Northampton Town.
First round draw of the Capital One Cup:
Derby County v Scunthorpe United
Rochdale v Barnsley
Port Vale v Burnley
Notts County v Bradford City
Hull City v Rotherham United
Fleetwood Town v Nottingham Forest
Carlisle United v Accrington Stanley
Doncaster Rovers v York City
Crewe Alexandra v Hartlepool United
Bury v Middlesbrough
Chesterfield v Tranmere Rovers
Sheffield United v Burton Albion
Blackpool v Morecambe
Leeds United v Shrewsbury Town
Preston North End v Huddersfield Town
Oldham Athletic v Sheffield Wednesday
Cheltenham Town v Milton Keynes Dons
Ipswich Town v Bristol Rovers
Stevenage v AFC Wimbledon
Exeter City v Crystal Palace
Yeovil Town v Colchester United
Birmingham City v Barnet
Bristol City v Gillingham
Northampton Town v Cardiff City
Plymouth Argyle v Portsmouth
Wolverhampton Wanderers v Aldershot Town
Walsall v Brentford
Millwall v Crawley Town
Torquay United v Leicester City
Dagenham & Redbridge v Coventry City
Peterborough United v Southend United
Swindon Town v Brighton & Hove Albion
Watford v Wycombe Wanderers
Charlton Athletic v Leyton Orient
Oxford United v AFC Bournemouth
Ties to be played week commencing 13th August 2012, however, if mutually agreed, The League will consider requests to play on Saturday 11th or Sunday 12th August 2012
The adidas Nitrocharge is the most talked about new cleat in years. It was released on May 15 and will take your pitch by storm.
One of the top soccer cleats for control the Nike CTR360 will not let you down on the field in tight spaces.
The Liverpool 2013/14 soccer jersey is available for pre-order. The Reds are eager to compete for silver next season.
adidas has added some color to the Predator line with this new colorway. Released on May 17. Be the first to own a pair.
The Juventus jersey for the 2013/14 was released earlier this week. Be the first to wear the colors of the Old Lady.
Bayern Munich are kings of Germany and hope to be crowned kings of Europe at Wembley later this month!
Ajax has released their away soccer jersey for the 2013/14 season. Get in the Gear.
Borussia Dortmund hears Wembley Calling and are headed to London for the Champions League final.
The push for more color on their cleats, adidas has added the infrared colorway to the adiZero f50 Line.
Chelsea won the Europa League on Wednesday. The Blues defeated Benfica 2-1 on injury time goal from Ivanovic.